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Chem 221 Notes | ||||||
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1 Gases 2 Microscopic Energies 3 First Law 4 2nd & 3rd Law 5 Phase transitions 6 Mixtures 7 Phase Diagrams 8 Equilibrium 9 Molecular Interactions |
Ternary Phase diagramsOften, solutions are made with more than two components in significant amount. This some times leads to phase issues that require a new kind of phase diagram to represent. A Ternary Phase Diagram shows the phases of a three component system. Normally, we represent these phases in a triangular diagram where the apices of the triangle represent the three pure components and the distance from an apex is a measure of it's concentration.
Taken from http://home.c2i.net/astandne/help_htm/english/terplot1.htm Here, we see a triangle for a system A,B,C. If A is the top apex then the baseline BC represents the 2-component phase diagram between B and C. Similarly, the edge opposite B is the two component AC region, etc. any point on the diagram represents the composition of the three components. Consider, first, a two-component water/dimethyl ether system. If we consider only these two solvents, we find that they are immiscible over a large concentration range 0.34 < mass fraction < 0.95. If we add at least 6% ethyl alcohol, we can make the solution totally miscible over the whole concentration range for the water/dimethyl ether.
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Last updated:
07-Apr-2010