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Ralph Whitney:  Publications

Dr. Whitney's Research Page

SM Malmberg, RA Whitney, JS Parent, "Nucleophilic Catalysis of Halide Displacement from Brominated Poly(isobutylene-co-isoprene)" European Polymer Journal; accepted for publication Dec. 18, 2009.
 
McLean, J. Keith; Guillen-Castellanos, Sergio A.; Parent, J. Scott; Whitney, Ralph A.; Kulbaba, Kevin; Osman, Akhtar.  Phase-Transfer Catalyzed Esterification of Brominated Poly(Isobutylene-co-Isoprene).  Industrial & Engineering Chemistry Research (2009),  48(24),  10759-10764.
                               
A Chan, RA Whitney, R Neufeld. "Semi-synthesis of controlled stimuli-responsive alginate hydrogel". Biomacromolecules  (2009),  10(3),  609-616.

A. Chan, R.A. Whitney, R. Neufeld "Kinetic controlled systhesis of pH-responsive network alginate", Biomacromolecules 9(9), 2536-2545 (2008).

Y. Cui, S. Kwok, A. Bucholtz, B. Davis, R.A. Whitney, P.G. Jessop"The Effect of Substitution on the Utility of Piperidines and Octahdroindoles for Reversible Hydrogen Storage", New Journal of Chemistry 32, 1027-1037 (2008).

SA Guillen-Castellanos, JS Parent, RA Whitney. "Synthesis of Ester Derivatives of Brominated Poly(isobutylene-co-isoprene): Solvent-free Phase Transfer Catalysis", Macromolecules. 39 (7), 2514-2520 (2006).

SA Guillen-Castellanos, JS Parent, RA Whitney. "Synthesis and Characterization of Ether Derivatives of Brominated Poly(isobutylene-co-isoprene)", Journal of Polymer Science Part A: Polymer Chemistry, 44 (2), 983-992 (2006).

JS Parent, A Liskova, RA Whitney, R Resendes, "Ion-dipole Interaction Effects in Isobutylene-based Ammonium Bromide Ionomers", Journal of Polymer Science Part A: Polymer Chemistry, 43(22), 5671-5679 (2005).

RA Whitney, A Penciu, JS Parent, R Resendes, W Hopkins; “Cross-Linking of Brominated Poly(isobutylene-co-Isoprene) by N-Alkylation of the Amidine Bases DBU and DBN”, Macromolecules 38, 4625-4629 (2005).

JS Parent, A Penciu, SA Guillen-Castellanos, A Liskova, and RA Whitney;  “Synthesis and Characterization of Isobutylene-based Ammonium and Phosphonium Bromide Ionomers”, Macromolecules 37, 7477-7483 (2004).

JS Parent, GDF White, D Thom, RA Whitney and W Hopkins; “Sulfuration and Reversion Reactions of Brominated Poly(isobutylene-co-isoprene)”, Journal of Polymer Science:Part A, Polymer Chemistry 41, 1915-1926 (2003).

ME Scott, JS Parent, J Dupont and RA Whitney; “Controlled Radical Grafting: Nitroxyl-Mediated Maleation of Model Hydrocarbons”, Industrial & Engineering Chemistry Research 42, 3662-3670, (2003).

M Spencer, JS Parent and RA Whitney; “Composition Distribution in Poly(ethylene-graft-vinyltrimethoxysilane)”, Polymer 44, 2015-2023 (2003).

Parent, J. Scott; Cirtwill, Stacey; Penciu, Anca; Whitney, Ralph A.; Jackson, Peter.
2,3-Dimethyl-2,3-diphenylbutane mediated grafting of vinyltriethoxysilane to polyethylene: a novel radical initiation system. Polymer (2003), 44(4), 953-961.

Spencer, Mark; Parent, J. Scott; Whitney, Ralph A.. Composition distribution in poly(ethylene-graft-vinyltrimethoxysilane). Polymer (2003), 44(7), 2015-2023.

Scott, Mark E.; Parent, J. Scott; Dupont, John; Whitney, Ralph A.. Controlled Radical Grafting: Nitroxyl-Mediated Maleation of Model Hydrocarbons. Industrial & Engineering Chemistry Research (2003), 42(16), 3662-3670.

Parent, J. Scott; White, Greg D. F.; Thom, Darren J.; Whitney, Ralph A.; Hopkins, William. Sulfuration and reversion reactions of brominated poly(isobutylene-co-isoprene). Journal of Polymer Science, Part A: Polymer Chemistry (2003), 41(13), 1915-1926.

Parent, J. Scott; White, Greg D. F.; Whitney, Ralph A.; Hopkins, William. Amine Substitution Reactions of Brominated Poly(isobutylene-co-isoprene): New Chemical Modification and Cure Chemistry. Macromolecules (2002), 35(9), 3374-3379.

Parent, J. Scott; Scott, Mark E.; Cunningham, Michael F.; Whitney, Ralph A.. Determination of alkoxyamine concentration in nitroxyl-mediated styrene polymerization products. Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) (2002), 43(2), 90-91.

Scott, Mark E.; Parent, J. Scott; Hennigar, Stephen L.; Whitney, Ralph A.; Cunningham, Michael F. Determination of Alkoxyamine Concentrations in Nitroxyl-Mediated Styrene Polymerization Products. Macromolecules (2002), 35(20), 7628-7633.

Parent, J. Scott; Spencer, Mark; Whitney, Ralph A.. Influence of hydrogen donors on peroxide-initiated melt grafting of vinylsilane to poly(ethylene-co-vinyl acetate). Journal of Applied Polymer Science (2002), 83(11), 2397-2402.

Parent, J. Scott; White, Greg D. F.; Whitney, Ralph A.. Synthesis of thioether derivatives of brominated poly(isobutylene-co-isoprene): direct coupling chemistry for silica reinforcement. Journal of Polymer Science, Part A: Polymer Chemistry (2002), 40(17), 2937-2944.

Parent, J. Scott; Thom, Darren J.; White, Greg; Whitney, Ralph A.; Hopkins, William. Thermal stability of brominated poly(isobutylene-co-isoprene). Journal of Polymer Science, Part A: Polymer Chemistry (2001), 39(12), 2019-2026.

Clark, D. C.; Baker, W. E.; Russell, K. E.; Whitney, R. A.. Dual monomer grafting of styrene and maleic anhydride onto model hydrocarbon substrates. Journal of Polymer Science, Part A: Polymer Chemistry (2000), 38(13), 2456-2468.

Hoo, V. M.; Whitney, R. A.; Baker, W. E. Free-radical grafting of co-monomer systems onto an ester-containing polymer. Polymer (2000), 41(11), 4367-4371.

Clark, D. C.; Baker, W. E.; Whitney, R. A.. Peroxide-initiated comonomer grafting of styrene and maleic anhydride onto polyethylene: effect of polyethylene microstructure. Journal of Applied Polymer Science (2000), Volume Date 2001, 79(1), 96-107.

Parent, J. S.; Geramita, K.; Ranganathan, S.; Whitney, R. A.. Silane-modified poly(ethylene-co-vinyl acetate): influence of comonomers on peroxide-initiated vinylsilane grafting. Journal of Applied Polymer Science (2000), 76(8), 1308-1314.

Ranganathan, S.; Baker, W. E.; Russell, K. E.; Whitney, R. A.. Peroxide initiated maleic anhydride grafting: structural studies on an ester-containing copolymer and related substrates. Journal of Polymer Science, Part A: Polymer Chemistry (1999), 37(11), 1609-1618.

Ranganathan, S.; Baker, W. E.; Russell, K. E.; Whitney, R. A.. Peroxide-initiated grafting of maleic anhydride onto linear and branched hydrocarbons. Journal of Polymer Science, Part A: Polymer Chemistry (1999), 37(20), 3817-3825.

Ranganathan, S.; Baker, W. E.; Russell, K. E.; Whitney, R. A.. Peroxide initiated melt grafting of maleic anhydride onto ethylene-methyl acrylate copolymers. Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) (1997), 38(2), 460-461.

Forsyth, J. C.; Baker, W. E.; Russell, K. E.; Whitney, R. A.. Peroxide-initiated vinylsilane grafting: structural studies on a hydrocarbon substrate. Journal of Polymer Science, Part A: Polymer Chemistry (1997), 35(16), 3517-3525.

Kimmett, Susan M.; Whitney, Ralph A.; Marks, Gerald S. Isolation of N-vinylprotoporphyrin IX after hepatic cytochrome P450 inactivation by 3-[(arylthio)ethyl]sydnone in chick embryos pretreated with phenobarbital, glutethimide, dexamethasone, and b-naphthoflavone: differential inhibition of ferrochelatase by N-vinylprotoporphyrin regioisomers. Molecular Pharmacology (1996), 49(4), 676