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Gregory Jerkiewicz:  Publications

Dr. Jerkiewicz's Research Page

A. Munro, M. F. Cunningham, G. Jerkiewicz, “Spectral and Physical Properties of Electrochemically Formed Colored Layers on Titanium Covered with Clearcoats”, ACS Applied Materials and Interfaces, accepted (January 2011).

G. Jerkiewicz, G. Vatankhah, S. Tanaka, J. Lessard, “Discovery of the Potential of Minimum Mass for Platinum Electrodes”, Langmuir, accepted (February 2011).

G. Jerkiewicz, “Electrochemical Hydrogen Adsorption and Absorption. Part 1: Under-Potential Deposition of Hydrogen”, Electrocatalysis, 1 (2010) 179 – 199.

M. D. Obradovic, J. Lessard, G. Jerkiewicz, “Cyclic-Voltammetry Behavior of Pt(111) in aqueous HClO4 + C6H6: Influence of C6H6 Concentration, Scan Rate and Temperature”, Journal of Electroanalytical Chemistry, 649 (2010) 248 – 256.

J. A. Keith, G. Jerkiewicz, T. Jacob, “Theoretical investigations of the oxygen reduction reaction on Pt(111)”, ChemPhysChem, 11 (2010) 2779 – 2794.

A. Munro, M. F. Cunningham, G. Jerkiewicz, “Influence of Clearcoats on the Spectral and Physical Properties of Electrochemically Formed Colored Passive Layers on Zirconium”, ACS Applied Materials and Interfaces, 2 (2010) 854 – 862.

S. Tanaka, H. Tobimatsu, Y. Maruyama, T. Tanaki, G. Jerkiewicz, “Preparation and Characterization of Microporous Layers on Titanium”, ACS Applied Materials and Interfaces, 1 (2009) 2312 – 2319.

G. Jerkiewicz, F. Perreault, Z. Radovic-Hrapovic, “Effect of Temperature Variation on the Under-Potential Deposition of Copper on Pt(111) in Aqueous H2SO4”, Journal of Physical Chemistry C, 113 (2009) 12309 – 12316.

G. Jerkiewicz, M. Alsabet, M. Grden, H. Varela, G. Tremiliosi-Filho, “Erratum to: ‘Comprehensive Study of the Growth of Thin Oxide Layers on Pt Electrodes under Well-Defined Temperature, Potential, and Time Conditions’”, Journal of Electroanalytical Chemistry, 625 (2009) 172 – 174.

J. Lessard, M. Obradovic, G. Jerkiewicz, (2009) “New Insight into the Electrocatalytic Hydrogenation of Model Unsaturated Organic Compounds”, in Catalysis of Organic Reactions, Ed. M. Prunier, CRC press, Vol. 123, pp. 149-158.

G. Jerkiewicz, B. Zhao, S. Hrapovic, B.L. Luan, "Discovery of Reversible Switching of Coloration of Passive Layers on Titanium", Chemistry of Materials, 20 (2008) 1877-1880.

M. Grdin, M. Lukaszewski, G. Jerkiewicz, A. Czerwinski, "Electrochemical Behaviour of Palladium Electrode: Oxidation, Electrodissolution and Ionic Absorption", Electrochimica Acta, 53 (2008) 7583-7598

A. Fonseca Lucredio, G. Jerkiewicz, E. Moreira Assaf, "Cobalt Catalysts Promoted with Cerium and Lanthanum Applied to Partial Oxidation of Methane Reactions" Applied Catalysis B, 84 (2008) 106-111.

M. Obradovic, G. Jerkiewicz, J. Lessard, " Towards Molecular-Level Understanding of Electrocatalytic Hydrogenation. A Comparison of Cyclic Voltammetry Behaviour of Benzene at Pt(111) Single Crystal Electrodes in Aqueous HCIO4 ", ECS Transactions, 13 (2008) 17-24; Ed. K. Moeller, Phoenix, Arizona, Vol. 13 (2008).

A. Fonseca Lucrédio, G. Jerkiewicz, E. Moreira Assaf, Applied Catalysis A: General, 33 (2007) 90-95.

B.D. Zhao, G. Jerkiewicz, "Electrochemically Formed Passive Layers on Titanium: Preparation and Biocompatibility Assessment in Hank's Balanced Salt Solution", Canadian Journal of Chemistry, 84 (2006) 1132-1145.

M. Alsabet, M. Grden, G. Jerkiewicz Comprehensive Study of the Growth of Thin Oxide Layers on Pt Electrodes under Well-Defined Temperature, Potential, and Time Conditions, Journal of Electroanalytical Chemistry 589 (2006) 120 - 127.

G. Jerkiewicz, Z. Radovic-Hrapovic, F. Perreault, “Thermodynamics of the Under-Potential Deposition of Silver on Pt(111) in Aqueous H2SO4”, Langmuir (in preparation, 2005).

M. DeBlois, J. Lessard, G. Jerkiewicz, “Influence of Benzene on the HUPD and Anion Adsorption on Pt(110), Pt(100) and Pt(111) Electrodes in Aqueous H2SO4”, Electrochimica Acta, 50 (2005) 3517 – 3523.

G. Jerkiewicz, M. DeBlois, Z. Radovic-Hrapovic, J.-P. Tessier, F. Perreault, J. Lessard, “Research on the Influence of Chemisorbed Benzene on the Under-Potential Deposition of Hydrogen on Pt(111) Electrode in Aqueous H2SO4”, Langmuir, 21 (2005) 3511 – 3520.

G. Tremiliosi-Filho, L.-H. Dall’Antonia, G. Jerkiewicz, “Growth of Surface Oxides on Gold Electrodes under Well-Defined Potential, Time, and Temperature Conditions”, Journal of Electroanalytical Chemistry, 578 (2005) 1 – 8.

E. Herrero, B. Alvarez, J. M. Feliu, S. Blais, Z. Radovic-Hrapovic, G. Jerkiewicz, “Temperature dependence of the COads oxidation process on Pt(111), Pt(100), and Pt(110) electrodes”, Journal of Electroanalytical Chemistry 567 (2004) 139-149.

G. Jerkiewicz, G. Vatankhah, J. Lessard, M. P. Soriaga, Y.-S. Park, “Surface-Oxide Growth at Platinum Electrodes in Aqueous H2SO4. Reexamination of Its Mechanism through Combined Cyclic-Voltammetry, Electrochemical Quartz-Crystal Nanobalance, and Auger Electron Spectroscopy Measurements", Electrochimica Acta, 49 (2004) 1451-1459.

B. E. Conway, A. Zolfaghari, W. G. Pell, G. Jerkiewicz,
"Voltammetry, nanogravimetry, and double-layer capacitance studies on chemisorption of Cl- and Br-, competitive with potential-dependent electrosorption of O species at Pt Electrodes", Electrochimica Acta, 48 (2003) 3775-3778.

Vatankhah, G.; Lessard, J.; Jerkiewicz, G.; Zolfaghari, A.; Conway, B. E. Dependence of the reliability of electrochemical quartz-crystal nanobalance mass responses on the calibration constant, Cf : analysis of three procedures for its determination. Electrochimica Acta (2003), 48(11), 1613-1622.

Conway, B. E.; Zolfaghari, A.; Pell, W. G.; Jerkiewicz, G.. Voltammetry, nanogravimetry and double-layer capacitance studies on chemisorption of Cl- and Br-, competitive with potential-dependent electrosorption of O species at Pt electrodes. Electrochimica Acta (2003), 48(25-26), 3775-3778.

Qian, S. Y.; Conway, B. E.; Jerkiewicz, G.. Authors' response to comments by A. Lasia on the paper - Comparative effects of adsorbed S-species on H sorption into Pd from UPD and OPD; a kinetic analysis. International Journal of Hydrogen Energy (2002), 27(3), 347-348.

Zolfaghari, Alireza; Conway, Brian E.; Jerkiewicz, Gregory. Elucidation of the effects of competitive adsorption of Cl-and Br- ions on the initial stages of Pt surface oxidation by means of electrochemical nanogravimetry. Electrochimica Acta (2002), 47(8), 1173-1187.

Conway, B. E.; Jerkiewicz, G.. Nature of electrosorbed H and its relation to metal dependence of catalysis in cathodic H2 evolution. Solid State Ionics (2002), 150(1,2), 93-103.

Blais, Sonia; Jerkiewicz, Gregory; Herrero, Enrique; Feliu, Juan M. New insight into the electro-oxidation of the irreversibly chemisorbed bismuth on Pt(111) through temperature-dependent research. Journal of Electroanalytical Chemistry (2002), 519(1-2), 111-122.

Radovic-Hrapovic, Zorana; Tessier, Jean-Pierre; Jerkiewicz, Gregory; Lessard, Jean. Towards molecular-level understanding of electrocatalytic hydrogenation. Part 1. Behavior of benzene at Pt(111). Proceedings - Electrochemical Society (2002), 2002-10(Organic Electrochemistry), 138-141.

Jerkiewicz, Gregory. Electro-adsorbed hydrogen and hydrogen electrocatalysis. Proceedings - Electrochemical Society (2001), 2000-20(Global Climate Change), 25-39.

Dall'Antonia, L. H.; Tremiliosi-Filho, G.; Jerkiewicz, G.. Influence of temperature on the growth of surface oxides on palladium electrodes. Journal of Electroanalytical Chemistry (2001), 502(1-2), 72-81.

Hrapovic, S.; Luan, B. L.; D'Amours, M.; Vatankhah, G.; Jerkiewicz, G.. Morphology, Chemical Composition, and Electrochemical Characteristics of Colored Titanium Passive Layers. Langmuir (2001), 17(10), 3051-3060.

Jerkiewicz, Gregory; Radovic-Hrapovic, Zorana. Silver UPD on Pt(111) in H2SO4: Temperature-dependence of the process. Abstracts of Papers - American Chemical Society (2001), 221st COLL-093.

Blais, Sonia; Jerkiewicz, Gregory; Herrero, Enrique; Feliu, Juan M. Temperature-Dependence of the Electro-oxidation of the Irreversibly Chemisorbed As on Pt(111). Langmuir (2001), 17(10), 3030-3038.

Radovic-Hrapovic, Z.; Jerkiewicz, G.. The temperature dependence of the cyclic-voltammetry response for the Pt(110) electrode in aqueous H2SO4 solution. Journal of Electroanalytical Chemistry (2001), 499(1), 61-66.

Qian, S. Y.; Conway, B. E.; Jerkiewicz, G.. Comparative effects of adsorbed S-species on H sorption into Pd from UPD and OPD H: a kinetic analysis. International Journal of Hydrogen Energy (2000), 25(6), 539-550.

Qian, S. Y.; Conway, B. E.; Jerkiewicz, G.. Kinetic analysis of effects of adsorbed S-species on H sorption into Pd from UPD and OPD H. Proceedings - Electrochemical Society (2000), 2000-16(Hydrogen at Surface and Interfaces), 98-114.

Conway, B. E.; Jerkiewicz, G.. Location of the Pt metals on the volcano curve for H2-evolution kinetics in relation to UPD and OPD states of adsorbed H. Proceedings - Electrochemical Society (2000), 2000-16(Hydrogen at Surface and Interfaces), 1-11.

Conway, B. E.; Jerkiewicz, G.. Relation of energies and coverages of underpotential and overpotential deposited H at Pt and other metals to the "volcano curve" for cathodic H2 evolution kinetics. Electrochimica Acta (2000), 45(25-26), 4075-4083.

Herrero, Enrique; Feliu, Juan M.; Blais, Sonia; Radovic-Hrapovic, Zorana; Jerkiewicz, Gregory. Temperature dependence of CO chemisorption and its oxidative desorption on the Pt(111) electrode. Langmuir (2000), 16(11), 4779-4783.

Jerkiewicz, G.. The oxidation mechanisms of transition-metal electrodes. A review. Environmentally Induced Cracking of Metals, Proceedings of the International Symposium, Ottawa, ON, Canada, Aug. 20-23, 2000 (2000), 177-189.

Dall'Antonia, L. H.; Tremiliosi-Filho, G.; Jerkiewicz, G.. The temperature effect on the growth of thin palladium oxide films. Proceedings - Electrochemical Society (2000), 2000-4(Oxide Films), 389-398.

Jerkiewicz, Gregory; Vatankhah, Gholam; Zolfaghari, Alireza; Lessard, Jean. Analysis of the mass response of the electrochemical quartz-crystal nanobalance in horizontal and vertical geometry. Electrochemistry Communications (1999), 1(9), 419-424.

Qian, S. Y.; Conway, B. E.; Jerkiewicz, G.. Electrochemical sorption of H into Fe and mild-steel: kinetic conditions for enhancement or inhibition by adsorbed HS-. Physical Chemistry Chemical Physics (1999), 1(11), 2805-2813.

Zolfaghari, Alireza; Jerkiewicz, Gregory; Chrzanowski, Wojciech; Wieckowski, Andrzei. Energetics of the underpotential deposition of hydrogen on platinum electrodes. II. Presence of coadsorbed sulfur. Journal of the Electrochemical Society (1999), 146(11), 4158-4165.

Attard, Gary A.; Ahmadi, Ahmad; Feliu, Juan; Rodes, Antonio; Herrero, Enrique; Blais, Sonia; Jerkiewicz, Gregory. Temperature Effects in the Enantiomeric Electro-Oxidation of D- and L-Glucose on Pt{643}S. Journal of Physical Chemistry B (1999), 103(9), 1381-1385.

Zolfaghari, Alireza; Jerkiewicz, Gregory. Temperature-dependent research on Pt(111) and Pt(100) electrodes in aqueous H2SO4. Journal of Electroanalytical Chemistry (1999), 467(1,2), 177-185.

Sung, Y.-E.; Chrzanowski, W.; Wieckowski, A.; Zolfaghari, A.; Blais, S.; Jerkiewicz, G.. Coverage evolution of sulfur on Pt(111) electrodes: from compressed overlayers to well-defined islands. Electrochimica Acta (1998), 44(6-7), 1019-1030.

Jerkiewicz, Gregory. Hydrogen sorption at/in electrodes. Progress in Surface Science (1998), 57(2), 137-186.

Qian, S. Y.; Conway, B. E.; Jerkiewicz, G.. Kinetic rationalization of catalyst poison effects on cathodic H sorption into metals: relation of enhancement and inhibition to H coverage. Journal of the Chemical Society, Faraday Transactions (1998), 94(19), 2945-2954.

Zolfaghari, Alireza; Chayer, Martine; Jerkiewicz, Gregory. Energetics of the underpotential deposition of hydrogen on platinum electrodes. I. Absence of coadsorbed species. Journal of the Electrochemical Society (1997), 144(9), 3034-3041.

Jerkiewicz, Gregory. From electrochemistry to molecular-level research on the solid-liquid electrochemical interface. An overview. ACS Symposium Series (1997), 656(Solid-Liquid Electrochemical Interfaces), 1-12.

Zolfaghari, Alireza; Jerkiewicz, Gregory. Fundamental thermodynamic aspects of the underpotential deposition of hydrogen, semiconductors, and metals. ACS Symposium Series (1997), 656(Solid-Liquid Electrochemical Interfaces), 45-60.

Zolfaghari, A.; Villiard, F.; Chayer, M.; Jerkiewicz, G.. Hydrogen adsorption on Pt and Rh electrodes and blocking of adsorption sites by chemisorbed sulfur. Journal of Alloys and Compounds (1997), 253-254 481-487.

Zolfaghari, Alireza; Jerkiewicz, Gregory. Hydrogen adsorption on Pt(111) and Pt(100) electrodes in aqueous H2SO4 solution. Temperature dependence studies. Proceedings - Electrochemical Society (1997), 97-16(Electrochemical Surface Science of Hydrogen Adsorption and Absorption), 133-158.

Zolfaghari, Alireza; Blais, Sonia; Jerkiewicz, Gregory. Influence of the electrolyte composition on thermodynamics of hydrogen adsorption on Pt electrodes. Aqueous H2SO4 vs. aqueous HClO4. Proceedings - Electrochemical Society (1997), 97-16(Electrochemical Surface Science of Hydrogen Adsorption and Absorption), 88-100.

Tremiliosi-Filho, G.; Dall'Antonia, L. H.; Jerkiewicz, G.. Limit to extent of formation of the quasi-two-dimensional oxide state on Au electrodes. Journal of Electroanalytical Chemistry (1997), 422(1-2), 149-159.

Zolfaghari, Alireza; Jerkiewicz, Gregory. New findings on hydrogen and anion adsorption at a Pt(111) electrode in aqueous H2SO4 solution generated by temperature variation. Journal of Electroanalytical Chemistry (1997), 422(1-2), 1-6.

Qian, S. Y.; Gao, L. J.; Conway, B. E.; Jerkiewicz, G.. Origin of enhancement of H sorption into iron and mild-steel by adsorbed As catalyst poison species. Proceedings - Electrochemical Society (1997), 97-16(Electrochemical Surface Science of Hydrogen Adsorption and Absorption), 180-199.

Sung, Y.-E.; Chrzanowski, W.; Zolfaghari, A.; Jerkiewicz, G.; Wieckowski, A. Structure of Chemisorbed Sulfur on a Pt(111) Electrode. Journal of the American Chemical Society (1997), 119(1), 194-200.

Villiard, Francis; Jerkiewicz, Gregory. Temperature dependence of growth of surface oxide films on rhodium electrodes. ACS Symposium Series (1997), 656(Solid-Liquid Electrochemical Interfaces), 323-341.

Zolfaghari, Alireza; Jerkiewicz, Gregory. The temperature dependence of hydrogen and anion adsorption at a Pt(100) electrode in aqueous H2SO4 solution. Journal of Electroanalytical Chemistry (1997), 420(1-2), 11-15.

Jerkiewicz, Gregory; Strzelecki, Henryk; Wieckowski, Andrzej. A New Procedure of Formation of Multicolor Passive Films on Titanium: Compositional Depth Profile Analysis. Langmuir (1996), 12(4), 1005-10.

Dall'Antonia, L. H.; Tremiliosi-Filho, G.; Jerkiewicz, G.. Characterization of different stages of surface oxides formed at gold by strong anodic polarization. Proceedings - Electrochemical Society (1996), 96-18(Surface Oxide Films), 292-302.

Jerkiewicz, Gregory; Zolfaghari, Alireza. Comparison of hydrogen electroadsorption from the electrolyte with hydrogen adsorption from the gas phase. Journal of the Electrochemical Society (1996), 143(4), 1240-8.

Conway, B. E.; Liu, T. C.; Jerkiewicz, G.. Coupling of high oxidation states with OH and O intermediates in O2 evolution at anodic oxide films. Proceedings - Electrochemical Society (1996), 95-26(Oxygen Electrochemistry), 132-54.

Jerkiewicz, Gregory; Zolfaghari, Alireza. Determination of the Energy of the Metal-Underpotential-Deposited Hydrogen Bond for Rhodium Electrodes. Journal of Physical Chemistry (1996), 100(20), 8454-61.

Zolfaghari, A.; Jerkiewicz, G.; Sung, Y.-E.; Wieckowski, A. Site-blocking on platinum electrodes by atomic sulfur: electrochemical and UHV studies. Proceedings - Electrochemical Society (1996), 96-8(Electrode Processes), 150-167.